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Citation: Zhen Jiaxiao, Chen Wenqi, Song Xiaopei. DIOXANE COMPLEXES OF QUADRIVALENT CERIUM CHLORIDES AND THEIR AMMONIUM SALTS[J]. Chinese Journal of Applied Chemistry, ;1986, 3(4): 42-47. shu

DIOXANE COMPLEXES OF QUADRIVALENT CERIUM CHLORIDES AND THEIR AMMONIUM SALTS

1.
1. Heilongjiang University;
2.
2. Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 20 May 1985
Available Online: 11 October 1985

The dioxane complexes of cerium(Ⅳ), Ce(C₄H₈O₂)₄Cl₄ or HCe(C₄H₈O₂)₄Cl₅ were prepared by gradually dissolving dried cerium (Ⅳ) hydroxide in dioxane (C₄H₈O₂)and then saturating with dried HCl gas. The formed solid complex was mixed with nitrogen-containing compounds (L), resulting a series of new complexes of ammonium pentachlorocerate (Ⅳ) (HL) Ce (C₄H₈O₂)_xCL₅ (L=8-hydroxy quinoline, imidazole,o-phenanthroline,pyridine, β-naphthoquinoline,phenazine; x=1,2,3,4). The complexes were characterized by elemental analyses, infrared spectra, ultra-violet spectra,thermal analysis and photoelectron spectra. The effects of the variety of nitrogencontaining ligands on the thermal stabilities of the complexes bave been primarily studied.
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