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Citation: Han Xiaozu, Wan Lianzhi, Guo Fengchun, Yang Xueyan, Zhang Qingyu. SYNTHESIS AND CHARACTERIZATION OF LIQUID CARBOXYL-TERMINATED POLYCHLOROPRENE AND ITS TOUGHENING EFFECT FOR EPOXY RESIN[J]. Chinese Journal of Applied Chemistry, ;1986, 3(2): 28-32. shu

SYNTHESIS AND CHARACTERIZATION OF LIQUID CARBOXYL-TERMINATED POLYCHLOROPRENE AND ITS TOUGHENING EFFECT FOR EPOXY RESIN

1.
Changchun Institute of Applied Chemistry, Academia Sinica

Received Date: 27 December 1984
Available Online: 3 April 1985

Liquid carboxyl-terminated polychloroprene(CTCP) was synthesized by means of emulsion polymerization using cyclohexone peroxide(CHPO)-ferrous sulfate as redox initiator.During polymerization process,chloroprene and CHPO solution were added to the reaction mixture continually. The results of IR and NMR determination of CTCP indcate that chloroprene units are mainly of trans 1,4-structure and connecte each other in the head-to-tail form. Epoxy resin could be toughened by this liquid rubber in certain extent.
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