Citation:
Xu Guanfan, Gao Lin, Fang Tianru, Wang Wenren, Zheng Yiji. WATER-SOLUBLE AND AMPHIPHILIC POLYMERS 13. SYNTHESIS OF LOW MOLECULAR WEIGHT POLY(ACRYLIC ACID) AND ITS SODIUM SALT[J]. Chinese Journal of Applied Chemistry,
;1992, 9(5): 77-79.
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Poly (acrylic acid) (PAA) and its sodium salt of low molecular weight were synthesized by using some redox initiator systems in which (NH4)2S2O8 was a main component. It was found that in acid solutions the resulted polymers were not crosslinked when FeSO4, CuSO4, or Na2S2O3 was present. In neutral solutions the (NH4)2S2O8-FeSO4-NaHSO3 ternary redox system was proved to be preferential for synthesizing low molecular weight PAA and conveniently controlling its molecular weight.
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