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Citation: Wang Mingzhao, Jin Linpei, Bünzli J. -C. G.. EUROPIUM(Ⅲ) ION AS LUMINESCENT PROBE: EUROPIUM(Ⅲ) SITE IN THE Eu(DMBM)(TPPO)₂(NO₃)₂[J]. Chinese Journal of Applied Chemistry, ;1992, 9(5): 60-64. shu

EUROPIUM(Ⅲ) ION AS LUMINESCENT PROBE: EUROPIUM(Ⅲ) SITE IN THE Eu(DMBM)(TPPO)₂(NO₃)₂

1.
1. Department of Chemistry, Beijng Normal University, Beijing 100875;
2.
2. Institute de Chimie Minerale et Analytique, Universite de Lausanne, Switzerland

Corresponding author: Wang Mingzhao,
Received Date: 17 September 1991
Available Online: 15 April 1992
Fund Project:

The two Eu(Ⅲ) sites of the Eu(DMBM)(TPPO)₂(NO₃)₂(DMBM:dimethoxybenzoylmethanate;TPPO;triphenyl phosphine oxide) have been probed high-resolution excltation and emission spectra at 77K on the powdered polycrystaline samples. Detailed study of ³D₁-⁷F₁(J=0~2) transitions. indicates the two sites with. C_2v, and C₁,C₂ or C symmetry respectively.The' Eu(l) site with C_2v predominates in the complex.
- luminescent probe,
- coordination compound,
- Eu(Ⅲ) site
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EUROPIUM(Ⅲ) ION AS LUMINESCENT PROBE: EUROPIUM(Ⅲ) SITE IN THE Eu(DMBM)(TPPO)2(NO3)2

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EUROPIUM(Ⅲ) ION AS LUMINESCENT PROBE: EUROPIUM(Ⅲ) SITE IN THE Eu(DMBM)(TPPO)₂(NO₃)₂