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Citation: Lü Zhengrong, Gao Songqi, Zhou Yaokun, Wu Shaozu. SYNTHESIS AND CHARACTERIZATION OF CYCLOPENTADIENYL (OR METHYLCYCLOPENTADIENYL)TITANIUM (Ⅳ) ZIRCONIUM(Ⅳ) TRISDITHIOCARBAMATES[J]. Chinese Journal of Applied Chemistry, ;1992, 9(3): 110-113. shu

SYNTHESIS AND CHARACTERIZATION OF CYCLOPENTADIENYL (OR METHYLCYCLOPENTADIENYL)TITANIUM (Ⅳ) ZIRCONIUM(Ⅳ) TRISDITHIOCARBAMATES

1.
1. Deparment of Chemistry, Department of Environmental Science, Wuhan University, Wuhan 430072;
2.
2. Department of Chemistry, Lanzhou University, Lanzhou
3.

Corresponding author: Lü Zhengrong,
Received Date: 25 June 1991
Available Online: 18 December 1991

Thirteen new compounds of type (RCp)M(S₂CNR₂)₃ were synthesized by reacting (RCp)₂MCl₂(R=H, Me;M=Ti(Ⅳ), Zr(Ⅳ)) with sodium pyrrolidine-, piperidine- and morpholine-dithiocarbamates, respectively. The IR spectra showed that the dithiocarhamic ligands behave as bidentate ligands in the complexes. The ¹H-NMR spectra showed that all complexes are rigid compounds.
- cyelopentadienyl,
- titanium,
- zirconium,
- dithiocarbamate
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