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Citation: Lin Fuqin, Fu Jianlong. CARBOXYLATION OF NITROTOLUENES[J]. Chinese Journal of Applied Chemistry, ;1987, 4(4): 49-52. shu

CARBOXYLATION OF NITROTOLUENES

Lin Fuqin ^, ,
Fu Jianlong

1.
Department of Chemistry, Xiangtan University, Hunan

Corresponding author: Lin Fuqin,
Received Date: 16 September 1986
Available Online: 31 October 1986
Fund Project:

A new approach has been worked out for carboxylation of nitrotoluene. o-Nitrotoluene or p-nitrotoluene was converted into the corresponding nitrophenylacetic acids by treatiag the nitro compound with alkaline salts of phenol and carbon dioxide in an aprotic dipolar solvent. The reaction occurs at 60-80℃ and atmospheric pressure and when mol ratio of alkaline salts of phenol with nitrotoluene attains 4:1, nitrophenylacetic acid. can be obtained quantitatively The carboxylation of m-nitrotoluene failed of success under the same conditions.
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