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Citation: Lu Yunjin, Zhu Zhonghe, Gu Da. THE CRYSTAL STRUCTURE OF DIETHYLETHANOLAMMONIUM BIS(O-DIPHENOLANTIMONATE(Ⅲ)[J]. Chinese Journal of Applied Chemistry, ;1987, 4(2): 61-64. shu

THE CRYSTAL STRUCTURE OF DIETHYLETHANOLAMMONIUM BIS(O-DIPHENOLANTIMONATE(Ⅲ)

1.
Modern Analysis Center of Nanging University

Corresponding author: Lu Yunjin,
Received Date: 23 January 1986
Available Online: 5 March 1986

The crystal of diethylthanolammonium bis (o-diphenol) antimonate (Ⅲ)belongs to orthorhombic space group P_2₁_2₁_2₁ with unit cell constants:a=9.096Å, b=11.636Å, c=17.786Å and Z=4. The coordinates of Sb atoms were derived from three-dimensional Patterson function and the locations of non-hydrogen atoms from succesive Fourier and difference Fourier syntheses.The structure was refined to R=0.0326, R_w=0.041 for 2106 independent reflections. It was considered that Sb atom makes use of four sp³d hybrid orbitals to conbine with four O Atoms in formation of a pesudo-trigonal bipyramidal configuration.
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