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Citation: Huang Saitang, Tang Rurong, Li Bing, Ding Anling. X-RAY PHOTOELECTRON SPECTROSCOPY STUDY OF N-OR P-COORDINATED TITANATE COMPLEXES[J]. Chinese Journal of Applied Chemistry, ;1988, 5(5): 30-33. shu

X-RAY PHOTOELECTRON SPECTROSCOPY STUDY OF N-OR P-COORDINATED TITANATE COMPLEXES

1.
Shanghai Institute of Organic Chemistry, Academia Sinica

Received Date: 16 July 1987
Available Online: 31 March 1988
Fund Project:

The N-or P-coordinated complexes of monoalkyl carboxyl and sulfonyl titanate were prepared.By means of XPS the N→Ti or P→Ti coordination bonds in these complexes were ascertained,and the relative bonding strength were estimated from the magnitude of the chemical shift data.The sulfonyl titanates are easier to be coordinated with N or P ligands, than the carboxyl titanates;and the hydroxysubstituted amines were coordinated easily with titanates;The chemical shifts of P-coordinated complexes were not pronounced as in the com-plexes with N-ligands.It may be caused by the "back donation" of Ti→P in these complexes. In addition,The intra-molecular N→Ti coordinate linkage has also been identified in the reaction products of isopropyl titanate and ethyl hydroxyl amines.
- titanate,
- N-coordinate,
- P-coordinate,
- Complex,
- XPS
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