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Citation: Zheng Jinghe, Jin Shongchun, Jin Zhungsheng, Jin Rizhen. MOLECULAR AND CRYSTAL STRUCTURE OF TETRA(p-METHOXY PHEHYL) PORPHYRIN MAHGANESE(Ⅲ) CHLORIDE COMPLEX[J]. Chinese Journal of Applied Chemistry, ;1988, 5(4): 50-53. shu

MOLECULAR AND CRYSTAL STRUCTURE OF TETRA(p-METHOXY PHEHYL) PORPHYRIN MAHGANESE(Ⅲ) CHLORIDE COMPLEX

1.
Changchun Institute of Applied Chemistry, Academia Sincia

Received Date: 23 February 1987
Available Online: 23 March 1987

The crystals of the title compound are orthorhombic with space group P_bca and a=23.3973(6)Å,b=22.5524(7)Å, c=15.1043(2)Å V=7970.02Å³, for Z=8.Diffracted intensities were collected on a Nicolet XRD R3 four-circle diffractometer using MoK_α radiation.The scanning technique was employed with a scan range 3° < 2θ < 45°.All independent reflections were 5200 among which 2859 reflections were observable (Ⅰ>3σ(Ⅰ)).The structure was determined by the heavy atom method and refined by block-diagonal matric least-square method.The average Mn-N bond length is 2.005Å and Mn-Cl bond length is 2.370(3)Å.
- Porphyrin complex,
- Crystal structure,
- X-ray diffractometry
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