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Citation: Jin Wenrui, Ren Yibing. ON THE PEAK CURRENT EQUATION FOR IRREVERSIBLE PROCESS ON A SPHERICAL ELECTRODE UNDER STIRRING[J]. Chinese Journal of Applied Chemistry, ;1988, 5(2): 93-95. shu

ON THE PEAK CURRENT EQUATION FOR IRREVERSIBLE PROCESS ON A SPHERICAL ELECTRODE UNDER STIRRING

Jin Wenrui ,
Ren Yibing

1.
Department of Chemistry, Shandong University, Ji'nan

Received Date: 19 September 1986
Available Online: 14 January 1987
Fund Project:

The peak current equation for irreversible process on a spherical electrode in a stirred solution for linear sweep adsorption voltammetry, corresponding to the case of a strong adsorption, can be expressed as follows i_p=i_p(t_a)+i_p(t_r)=K'vD²/³r_o²v^-1/₆ω^1/2t_aC^*+i_p(t_r) where i_p(t_a) is the peak current for the preconcentration time(t_a) in a stirred solution; i_p(t_r) is the peak current for the rest period, t_r,v is the scan rate; D is the diffusion coefficient; r_o is the radius of the spherical electrode; ω is the angular velocity of the solution; v is the kinematic viscosity, C^* is the bulk concentration of the, depolarizer; K' is a constant. The equation has been verified experimentally for system of Co(Ⅱ)-dimethylglyoxime in NH₃/NH₄Cl.
- Linear sweep adsorption voltammetry,
- Peak current equation
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