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Citation: Xu Baoqing, Xu Zhaohua, Bao Binian, Sun Bingfang, Zhang Huajie. PHASE CHANGE OF ZnS-CdS-BASED PHOSPHORS DURING SINTERING[J]. Chinese Journal of Applied Chemistry, ;1988, 5(2): 90-92. shu

PHASE CHANGE OF ZnS-CdS-BASED PHOSPHORS DURING SINTERING

1.
1. Department of Chemistry, Hangzhou University;
2.
2. Shaoxing Electron Tube Factory, Shaoxing, Zhejiang;
3.
3. Wenzhou Medical Institute Wenzhou, Zhejiang

Received Date: 11 May 1987
Available Online: 25 August 1987

The structure of(Cd_xZn_1-x) S:Ag obtained by sintering at 850℃ was determined by X-ray diffraction method. The solid solution is of homogeneous wurtzite over the range of 0.5 < x < 1, while the Zn-rich wurtzite structure is dominant for 0.3 < x < 0.5. With decrease of x from 0.3 to 0, the fraction of Zn-rich sphalerite increases gradually till all the structure becomes of sphalerite. The lattice parameters vary with the composition of the solution and it results in a variation of luminescence emission spectra. The phase transition from the sphalerite to wurtzite occurs at about 700℃ with simultaneous formation of the luminescence center.
- Cadium sulfide,
- Zinc sulfide,
- Phosphors
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