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Citation: Zhang Guomin, Xiong Heping, Zhang Lun. STUDIES ON BORON COMPOUNDS ⅩⅣ.SYNTHESIS OF PHENYLALANINE RARE EARTH METAL(Ⅲ) POLYHEDRAL BORANE CHELATES AND THEIR PROPERTIES[J]. Chinese Journal of Applied Chemistry, ;1984, 1(4): 40-44. shu

STUDIES ON BORON COMPOUNDS ⅩⅣ.SYNTHESIS OF PHENYLALANINE RARE EARTH METAL(Ⅲ) POLYHEDRAL BORANE CHELATES AND THEIR PROPERTIES

1.
Department of chemistry, Wuhan University, Wuhan

Received Date: 6 March 1984
Available Online: 6 June 1984

Eighteen new phenylalanine rare earth metal(Ⅲ) polyhedral borane che-lates have been prepared in high yield by the reaction of rare earth metal hydroborate [Ln₂(B_nH_n)₃, n=10 or 12] with DL-phenylalanine. The pro-ducts have been characterized by elemental analysis,IR spectra and electrical conductivity measurement. The results showed that in these compounds DL-phenylalanines are neutral ligands coordinated to rare earth ion through the nitrogen atom of amino group and the oxygen atom of carbonyl of carboxylic group.
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