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Citation: Zhu Baoku, Xu Zhikang, Xu Youyi. Synthesis of Tetra(4-nitrophenyl) porphyrin and Tetra(4-aminophenyl) porphyrin[J]. Chinese Journal of Applied Chemistry, ;1999, 16(1): 68-70. shu

Synthesis of Tetra(4-nitrophenyl) porphyrin and Tetra(4-aminophenyl) porphyrin

1.
Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027

Received Date: 1 June 1998
Available Online: 7 October 1998

An improved method for synthesis of tetra (4-nitrophenyl) porphyrin (TNPP) and tetra (4-aminophenyl) porphyrin (TAPP) is reported. 4-Nitrobenzaldehyde was cyclized with pyrrole in refluxing nitrobenzene using a lactic acid catalyst and then precipited by methanol giving TNPP of 22.3% yield in high purity. Reduction of TNPP with SnCl₂·2H₂O in concentrated HCl gave high purity TAPP in yield of 81.5%.
- tetra (nitrophenyl) porphyrin,
- tetra (aminophenyl) porphyrin,
- synthesis
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