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Citation: Liu Pu, Liu Ye, Yin Yuanqi. Selective Hydrogenation of Maleic Anhydride to Succinic Anhydride on PdCl₂/PPh₃[J]. Chinese Journal of Applied Chemistry, ;1999, 16(1): 58-61. shu

Selective Hydrogenation of Maleic Anhydride to Succinic Anhydride on PdCl₂/PPh₃

1.
Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000

Received Date: 9 May 1998
Available Online: 23 October 1998

A noval preparation method of succinic anhydride with high selectivity and conversion by homogeneous hydrogenation of maleic anhydirde has been successfully developed. Results show that among catalysts and ligands studied PdCl₂ is the best catalyst and PPh₃ is the most suitable ligand. The effects of n(PPh₃)/n (Pd), reaction temperature, hydorgen pressure, catalyst concentration and maleic concentration have been investigated. Under the typical reaction conditions: PdCl₂=1.25×10^-3 mol/L, n(MA)/n(Pd)=2000, n(PPh₃)/n(Pd)=4 in 8 mL ethylene glycoldimethyl ether at 373~393 K and hydrogen pressure of 2.5 MPa for 1 hour more, the conversion of meleic anhydride is 90% and the selectivity of succinic anhydride is 100%.
- maleic anhydride,
- homogeneous hydrogenation,
- PdCl₂ catalyst,
- triphenylphosphine,
- succinic anhydride
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Selective Hydrogenation of Maleic Anhydride to Succinic Anhydride on PdCl2/PPh3

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Selective Hydrogenation of Maleic Anhydride to Succinic Anhydride on PdCl₂/PPh₃