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Citation: Wu Jieying, Tian Yupeng, Xie Fuxin, Ni Shisheng. Synthesis, and Thirdorder Nonlinear Optical Property of Some Transition Metal Dithiocomplexes[J]. Chinese Journal of Applied Chemistry, ;1999, 16(1): 38-41. shu

Synthesis, and Thirdorder Nonlinear Optical Property of Some Transition Metal Dithiocomplexes

1.
Department of Chemistry, Anhui University, Hefei 230093

Received Date: 27 July 1998
Available Online: 14 October 1998
Fund Project: 国家自然科学基金(29871001) (29871001)

4-Aminophenyl ammonium dithiocarbam ate and their Ni(Ⅱ), Pd (Ⅱ)and Pt (Ⅱ) complexes have been synthesized and characterized. The complexes formed metall (Ⅱ) dithiocarbimates with tetrabutyl ammonium bromide in alcoholic NaOH solution. The spectral results indicated that both dithiocarbamate and dithiocarbimate complexes are bidentate ligand and have square planar configuration. The third-order nonlinear optical response results obtained by degenerate four-wave mixing technique showed that the dithiocarbim ate complexes have higher third-order nonlinear optical response due to high delocalization of the system.
- nickel,
- platinum,
- palladium,
- dithiocarbamate complex,
- dithicarbimate complex,
- thirdorder nonlinear optical property
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