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Citation: LIN Shen, WANG Shi-Ming, ZHENG Ying, LI Xiao-Jing. Catalytic Activity of Heteropoly Compound (NH₄)₁₁Gd[Gd₄Mo₂₉O₁₀₀(H₂O)₁₆]·33H₂O in Phenol Hydroxylation[J]. Chinese Journal of Applied Chemistry, ;2000, 17(2): 192-194. shu

Catalytic Activity of Heteropoly Compound (NH₄)₁₁Gd[Gd₄Mo₂₉O₁₀₀(H₂O)₁₆]·33H₂O in Phenol Hydroxylation

1.
Department of Chemistry, Fujian Normal University, Fuzhou 350007

Received Date: 13 September 1999
Available Online: 26 January 2000
Fund Project: 福建省科委资助课题(K99017) (K99017)

Title moly bdogadolinium hetero poly com pound ha s been synthesized and used to catalize the hydrox ylation of phenol with hydrogen peroxide. The effects of reaction time, tempera ture, pH value, n(phOH)/n(H₂O₂) and solvent on the cataly ticactivity for phenol hydrox ylation have been investigated. The results show that the titlecom pound in the presence of V₂O₅ shows an excellent catalytic activity for phenol hydroxylation. When methanol is used as solvent at n(phOH)/n(H₂O₂)=1:2, pH=5, at 343 K and for 4 h, hydroquino ne in yield of 42.10% is obtained with phenol conversion of 40.50%.
- phenol,
- hydrox ylation,
- hydroquinone,
- hydrogen peroxide,
- molybdogadolinium heteropoly compound
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沈阳化工大学材料科学与工程学院沈阳 110142

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Catalytic Activity of Heteropoly Compound (NH₄)₁₁Gd[Gd₄Mo₂₉O₁₀₀(H₂O)₁₆]·33H₂O in Phenol Hydroxylation