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Citation: YING Lai-Qiang, ZHAO Yu-Ying, BA Xiao-Wei, TANG Tao, JIN Ying-Tai. Polymerization of Acrylonitrile with Yttrocene-containing Aluminium Bimetallic Complex[J]. Chinese Journal of Applied Chemistry, ;2000, 17(5): 524-526. shu

Polymerization of Acrylonitrile with Yttrocene-containing Aluminium Bimetallic Complex

1.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 15 December 1999
Available Online: 9 May 2000
Fund Project: 国家重点基础研究"九七三"专项经费(G1999064801) (G1999064801)

The polymerization of acrylonitrile was first studied using (C₉H₇)₂Y(_-Et)₂ AlEt₂ as a single-component catalyst. The catalytic activity could be greatly increased when PhONa was added to the catalyst in amount of n(PhONa)/n(Cat)=3. A mechanism related to the polymerization initiation of AN is proposed.
- yttrocene-containing aluminium bimetallic complex,
- acrylonitrile,
- polymerization
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Polymerization of Acrylonitrile with Yttrocene-containing Aluminium Bimetallic Complex

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com