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Citation: DAI Li-Zong, XU Yi-Ting, ZOU You-Si, WU Hui-Huang. The Emulsion Polymerization of 2, 5-Dimethoxyaniline and The Characterization of Polymer Structure[J]. Chinese Journal of Applied Chemistry, ;2001, 18(4): 272-275. shu

The Emulsion Polymerization of 2, 5-Dimethoxyaniline and The Characterization of Polymer Structure

1.
College of Chemistry and Chemical Engineering, Xiamen University, State Key Laboratory of Physical Chemistry for Solid Surface, Xiamen 361005

Received Date: 10 June 2000
Available Online: 20 January 2001
Fund Project: 国家教育部博士点专项科研基金资助项目(1999038404) (1999038404)

The effects of temperature, concentrations of initiator (KPS) and emulsifier (SDS) on emulsion polymerization of 2,5 dimethoxyaniline (DMAn) were investigated. The polymer PDMAn with number average molecualr weight of 1.22×10⁴ was obtained in the conditions, [monomer]=6.0×10^-3 mol/L, [SDS]≥5.0×10^-2 mol/L, [KPS]=3.5×10^-3 mol/L, 85℃, for 2.0 h. ¹H NMR, FTIR and TEM techniques were used in structure characterization, the results showed that the polymer was produced by para polymerization and the ratio of benzoid to quinoid units was 3:1 in its macromolecular chain.
- polydimethoxyaniline,
- emulsion polymerization,
- polymer structure
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The Emulsion Polymerization of 2, 5-Dimethoxyaniline and The Characterization of Polymer Structure

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com