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Citation: ZHANG Yu-Liang, QIAN Ming-Xing, HE Ren. Ethylene Oligomerization Catalyzed by Transition Metal Complexes[J]. Chinese Journal of Applied Chemistry, ;2001, 18(5): 360-364. shu

Ethylene Oligomerization Catalyzed by Transition Metal Complexes

1.
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012

Received Date: 29 December 2000
Available Online: 12 March 2001
Fund Project: 国家自然科学基金(29773008)资助项目 (29773008)

Recent achievements in ethylene oligomerization by using transition metal complexes as catalysts are reviewed with emphases on the description of novel catalyst systems. The relationship between the behavior of catalysts in oligomerization and polymerization has been discussed. The oligomerization and polymerization of ethylene have readily identifiable mechanistic feature, difference is the rate of insertion and U-H elimination. M⁴⁺ (M=Ti,Zr) complexes mainly catalyze ethylene oligomerization, and M³⁺ (M=Ti,Zr) complexes catalyze polymerization. Altering the cocatalyst composition of group Ⅳ B metallocene catalyst systems and reaction conditions leads to oligomerization of ethylene. Group Ⅷ complexes with small volume of ligands favor the U-H elimination and oligomerization.
- ethylene,
- oligomerization,
- transition metal complexes,
- homogeneous catalysis
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