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Citation: KONG Qing-An, JIN Guo-Xin. Half-sandwich 1,3-Di-t-butylcyclopentadienyl Rhodium Complexes Containing Sulfido Ligands[J]. Chinese Journal of Applied Chemistry, ;2001, 18(5): 322-329. shu

Half-sandwich 1,3-Di-t-butylcyclopentadienyl Rhodium Complexes Containing Sulfido Ligands

1.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 29 December 2000
Available Online: 3 February 2001

Treatment of 1,3-di-t-butylcyclopentadiene with rhodium trichloride in EtOH leads to the formation of binuclear half-sandwich complex [Cp^t RhCl(_-Cl)]₂ (1) (Cp^t=Z⁵-^tBu₂C₅H₃) which reacts with trimethylphosphine to give Cp^t Rh(PMe₃)Cl₂ (2) in high yield. 2 reacts with ammonium polysulfide, (NH₄)₂S_x to give cyclooligosulfido half-sandwich complexes Cp^t Rh(PMe₃)(S_n)(n=4(4a),6(4b)). Desulfurization of 4b by excess PPh₃ results in cyclotetrasulfido product 4a, while 4a takes up sulfur from polysulfide to convert cyclohexasulfido product 4b. The reaction of 2 with Et₄NI gives diiodide complex 3 which is determined by single crystal X-ray crystallographic analysis.
- half-sandwich complex,
- rhodium,
- sulfur,
- desulfurization,
- metalla cyclo-oligosulfide,
- X-ray crystal structure
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