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Citation: YIN Wei, ZHANG Xiu-Lian, ZHANG Mai-Sheng. Study on Supramolecular System of the Host CP66 with Naphthalene Derivatives[J]. Chinese Journal of Applied Chemistry, ;2001, 18(6): 457-461. shu

Study on Supramolecular System of the Host CP66 with Naphthalene Derivatives

1.
a Department of Chemistry, Guangdong College of Education, Guangzhou;
2.
b School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou 510275

Received Date: 30 August 2000
Available Online: 5 December 2000
Fund Project: 中山大学科研基金(3200901)资助课题 (3200901)

The supramolecular systems of the host 1,8,22,29-tetra [8.1.8.1]-paracyclophane (CP66) with T-naphthol, U-naphthol, 2, 6-dihydroxyl naphthalene and 6,7-dihydroxyl naphthalen-2-sulfonic acid as guests have been studied by UV spectrometry, fluorescence probe and synchronous fluorimetry. The CP66 formed 1:1 stoichiometric supramolecular system for all naphthalene compounds. The complex formation reactions of CP66 with T-naphthol, 2,6-dihydroxyl naphthalene were enthalpy promoted, while the reactions of CP66 with U-naphthol and 6,7-dihydroxyl naphthalen-2-sulfonic acid were entropy promoted. The unchanged values of the constant K_s shows that the main contribution to the formation of supromolecular systems of the CP66 with 6,7-dihydroxyl naphthalene-sulfonic acid arises from the electrostatic attraction. The host CP66 is found to recognize the isomer of naphthol by using a fluorescence probe.
- azaparacyclophane,
- supramolecular system,
- molecular recognition
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