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Citation: ZHONG Guo-Qing, GUO Ying-Chen, LUAN Shao-Rong, ZANG Xiang-Sheng, CHE YA-Ru. Synthesis and Characterization of the Complexes Zinc(Ⅱ) with Schiff Base Ligands Derived from Salicylaldehyde and Non-Natural Amino Acids and Dipeptide[J]. Chinese Journal of Applied Chemistry, ;2001, 18(10): 817-820. shu

Synthesis and Characterization of the Complexes Zinc(Ⅱ) with Schiff Base Ligands Derived from Salicylaldehyde and Non-Natural Amino Acids and Dipeptide

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a Department of Basic Science, Sichuan Institute of Animal Husbandry and Veterinary Medicine, Chongqing 402460;
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b Department of Chemistry, Nanyang Teacher's College, Nanyang;
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c Department of Chemistry, East China University of Science and Technology, Shanghai

Received Date: 8 February 2001
Available Online: 26 April 2001
Fund Project: 重庆市教委自然科学基金资助项目(990505) (990505)

Two novel complexes of Zn(Ⅱ) with N-salicylidene p-methylsulfonyl phenyleneserine and N-salicylidene glycyl glycine have been synthesized. The compositions and structures of the complexes were characterized by elemental analyses, molar conductance, infrared spectra, TG DTA, X-ray powder diffraction. The compositions of two complexes are ZnC₁₇H₁₇O₇NS(A) and ZnC₁₁H₁₃-O_5.5 N₂(B). The complexes are nonelectrolyte having coordination water for A, but only crystal water for B. The coordination numbers of zinc ion in the complexes are four. The XRD indexes results indicated that the crystal structure of the complex A belongs to monoclinic system, with lattice parameters:a=1.623 3 nm, b=2.270 0 nm, c=1.669 3 nm, U=94.39°; and the complex B belongs to triclinic system, with lattice parameters:a=1.786 5 nm, b=1.684 1 nm, c=2.032 1 nm, T=96.96°, U=96.51°, V=98.73° respectively.
- p-methylsulfonyl-phenyleneserine,
- glycyl glycine,
- salicyladehyde,
- Schiff base,
- zinc(Ⅱ)complex
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