Citation:
LI Jian-Gang, TANG Zhi-Yuan, XUE Jian-Jun, LIU Chun-Yan. On the C-rate Performance of LiCrxMn2-xO4[J]. Chinese Journal of Applied Chemistry,
;2001, 18(10): 802-805.
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The C rate performance of LiCrxMn2-xO4 has been studied by the current pulse relaxation technique as a function of the lithium diffusion coefficients in LiCrxMn2-xO4. The results revealed that the increment of the doped chromium ion can accelerate the diffusion rate of lithium ion, reduce the Jahn-Tellar effects, and improve the rate capacity and cycle life at higher C rates for LiCrxMn2-xO4. LiCr0.1Mn1.9O4 showed the best electrochemical performance at 1C rate charge discharge cycles.
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