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Citation: LI Xu-Guang, GAO Ying, FENG Yu-Ying, XING Wei, YANG Hui, LU Tian-Hong. Electrocatalytic Behavior of Microperoxidase-11 Adsorbed on Active Carbon for Reduction of Oxygen and Hydrogen Peroxide[J]. Chinese Journal of Applied Chemistry, ;2002, 19(3): 285-289. shu

Electrocatalytic Behavior of Microperoxidase-11 Adsorbed on Active Carbon for Reduction of Oxygen and Hydrogen Peroxide

LI Xu-Guang ^a ,
GAO Ying ^b ,
FENG Yu-Ying ^c ,
XING Wei ^a ,
YANG Hui ^c ,
LU Tian-Hong ^c,,

1.
a Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun;
2.
b Department of Chemistry, Haerbin Normal Normal University, Haerbin;
3.
c Department of Chemistry, Nanj ing Normal University, Nanjing 210097

Corresponding author: LU Tian-Hong,
Received Date: 21 August 2001
Available Online: 24 December 2001
Fund Project: 科技部"973"(G2000026408) (G2000026408)国家自然科学基金(29973015) (29973015)黑龙江省自然科学基金(B2000-06) (B2000-06)江苏省教委自然科学基金(00KJB50007)资助项目 (00KJB50007)

Microperoxidase-11(MP-11) was adsorbed on active carbon by equilibrium adsorption method. The electrocatalytic behaviors of MP-11/C electrode for the reduction of O₂ and H₂O₂ were studied by cyclic voltammmetry and linear voltammmetry and RDE technique. The results showed that MP-11/C possessed good electrocatalytic activity for the reduction of O₂ and H₂O₂. And the mechanism of oxygen reduction is dependent on pH of the solution. It provides a reliable method for immobilization of enzymes and a promising catalyst for the reduction of O₂ in biofuel cell.
- microperoxide-11,
- oxygen,
- hydrogen peroxide,
- reduction
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