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Citation: HUANG Zhi-Hong, XIE Zhi-Ming, LI Zhuo-Mei. Studies on the Crosslinking of Acrylate Copolymer Soap-free Hydrosol with Zirconium Chelate ⅠEffects of Polymerization Conditions on the Property of Soap free Hydrosol[J]. Chinese Journal of Applied Chemistry, ;2002, 19(3): 220-223. shu

Studies on the Crosslinking of Acrylate Copolymer Soap-free Hydrosol with Zirconium Chelate ⅠEffects of Polymerization Conditions on the Property of Soap free Hydrosol

1.
Institute of Polymer Science, Zhongshan University, Guangzhou 510275

Corresponding author: HUANG Zhi-Hong,
Received Date: 17 May 2001
Available Online: 18 October 2001

The effects of the amount of hydrophilic monomer acrylic acid(AA) and initiator benzoyl peroxide(BPO) in polymerization of acrylate terpolymer (consisted of methylmethacrylate(MMA), butyl acrylate(BA) and acrylic acid) on the properties of the acrylate terpolymer soap free hydrosol have been studied. The optimum contents of h(AA) 4% and c (BPO) 1.8×10^-2g/mL were selected. The terpolymer was identified by IR, ¹H NMR and GPC. The hydrosol obtained had viscosity 20.5 mPa·s (D200s^-1), surface tension 31 mN/m and an improved stability, meeting the basic requirements of water based ink.
- soap-free hydrosol,
- acrylate terpolymer,
- hydrosol property
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