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Citation: CHEN Li, WANG Dao-Quan, JIN Shu-Hui. Synthesis and Fungicidal Activity of 2-(1,11-Undecylidene)-5-substituted imino-Δ³-1,3,4-thiadiazolines[J]. Chinese Journal of Applied Chemistry, ;2002, 19(3): 212-215. shu

Synthesis and Fungicidal Activity of 2-(1,11-Undecylidene)-5-substituted imino-Δ³-1,3,4-thiadiazolines

1.
College of Applied Chemistry, China Agricultural University, Beijing 100094

Corresponding author: JIN Shu-Hui,
Received Date: 23 April 2001
Available Online: 12 November 2001

N-substituted cyclododecanone thiosemicarbazones(4) were synthesized by condensation reaction of cyclododecanone and N-substituted thiosemicarbazide. 4 undergo oxidative cyclisation on treatment with manganese dioxide to give title compounds, 2-(1,11-undecylidene)-5-substituted imino Δ³-1,3,4-thiadiazoline(5). The structure of 5 were confirmed by IR, ¹³C NMR and elemental analysis. Preliminary bioassays showed that compounds 5 have some fungicidal activity.
- cyclododecanone,
- thiosemicarbozone,
- undecylidene-substituted imino thiadiazoline,
- synthesis,
- fungicidal activity
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Synthesis and Fungicidal Activity of 2-(1,11-Undecylidene)-5-substituted imino-Δ3-1,3,4-thiadiazolines

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Fungicidal Activity of 2-(1,11-Undecylidene)-5-substituted imino-Δ³-1,3,4-thiadiazolines