Citation:
LI Jing-Yin, GUO Yu-Feng, ZHANG Ya-Tong, WANG Ji-Zhi. Photocatalytic Degradation of 2,4-Dichlorophenol by TiO2/glass Film[J]. Chinese Journal of Applied Chemistry,
;2002, 19(5): 494-496.
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TiO2/glass film photocatalysts have been prepared by a sol-gel method with titanium tetrabutoxide as precursor, and used in photocatalytic degradation of 2,4-dichlorophenol(DCP) in aqueous solution. The experiments indicated that the TiO2/glass film coated with five layers of TiO2 sol in the case of higher pH value(≥10) or lower pH value(≤2) showed a higher catalytic activity, and the relationship between initial DCP concentration(c0) and reaction rate(r0) follows Langmuir Hinshelwood equation. The photocatalytic degradation kinetics of DCP(c0≤0.5 mmol/L) is of first order kinetics.
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Keywords:
- TiO2/glass film,
- photocatalytic degradation,
- dichlorophenol
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