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Citation: ZHONG Guo-Qing, LUAN Shao-Rong, CHEN Ya-Ru. Synthesis of Arsenic(Ⅲ) and Antimony(Ⅲ) Complexes by Solid Phase Reaction[J]. Chinese Journal of Applied Chemistry, ;2002, 19(9): 878-881. shu

Synthesis of Arsenic(Ⅲ) and Antimony(Ⅲ) Complexes by Solid Phase Reaction

1.
a Department of Chemistry, Southwest Agricultural University Rongchang Campus, Chongqing 402460;
2.
b Department of Chemistry, East China University of Science and Technology, Shanghai

Corresponding author: ZHONG Guo-Qing,
Received Date: 25 January 2002
Available Online: 9 May 2002

The cysteine(Cys) and thiourea(Tu) complexes with antimony and arsenic trihalide have been synthesized by solid phase reaction. The compositions and structures of the complexes have been characterized by elemental analysis, infrared spectra and X-ray powder diffraction. The complexes have compositions of ML₃X₃(M=As,Sb; L=Cys,Tu; X=I,Cl). They are stable at room temperature, nonhygroscopic and slightly soluble in water. The results indicate that the sulphur in cysteine, nitrogen in thiourea and chlorine or iodine atoms are coordinated with trivalent arsenic or antimony ion. The coordination numbers of arsenic and antimony ion in the complexes are six. The crystal of the complexes belongs to monoclinic system with a=1.1743 nm, b=0.6945 nm, c=1.6822 nm, U=95.28° for As(Cys)₃I₃; a=1.1119 nm, b=1.9030 nm, c=1.5410 nm, U=94.77° for As(Tu)₃I₃; a=1.2051 nm, b=0.6792 nm, c=1.6850 nm, U=95.79° for Sb(Cys)₃Cl₃; and a=1.2343 nm, b=1.6585 nm, c=1.9252 nm, U=96.46° for Sb(Tu)₃Cl₃, respectively.
- arsenic trihalide,
- antimony trihalide,
- cysteine,
- thiourea,
- complex,
- solid phase synthesis
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