Home

Citation: YANG Bing-Qin, GUO Yuan, WANG Yun-Xia. Synthesis of (4,4'-Diaminobiphenylene-2,2') disulfonic Acid[J]. Chinese Journal of Applied Chemistry, ;2002, 19(11): 1118-1119. shu

Synthesis of (4,4'-Diaminobiphenylene-2,2') disulfonic Acid

1.
Department of Chemistry, Northwest University, Xi'an 710069

Corresponding author: YANG Bing-Qin,
Received Date: 25 December 2001
Available Online: 24 July 2002
Fund Project: 陕西省自然科学基金资助项目(FF01202) (FF01202)

Sodium m-nitrobenzene sulfonate was reduced by formal solution to give disulfo azoxybenzene. The latter was reduced by an alkali solution of glucose at 94~96℃ for 5 hours to give hydrazobenzene disulfonic sodium (2). The title compound was obtained by rearrangement of (2) by hydrochloric acid in yield of 81.5%. The method has the advantages of cheapness and high yield.
- nitrobenzenesulfonate,
- diaminobiphenylene disulfonic acid,
- glucose,
- formaldehyde
1. [1]
  Zhuoyue Guo , Jinxin Guo . The Amazing Journey of Glucose. University Chemistry, 2026, 41(2): 279-285. doi: 10.12461/PKU.DXHX202502082
2. [2]
  Bin SUN , Heyan JIANG . Glucose-modified bis-Schiff bases: Synthesis and bio-activities in Alzheimer′s disease therapy. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1338-1350. doi: 10.11862/CJIC.20240428
3. [3]
  Yuena Yu , Fang Fang . Microwave-Assisted Synthesis of Safinamide Methanesulfonate. University Chemistry, 2024, 39(11): 210-216. doi: 10.3866/PKU.DXHX202401076
4. [4]
  Huairou Zhu , Qiaoyi Cen , Dan Yan , Wei Yi , Guosheng Chen , Siming Huang , Gangfeng Ouyang . 基于仿生矿化酶固定纳米探针对血清葡萄糖定量检测的实验新探索. University Chemistry, 2026, 41(5): 330-339. doi: 10.12461/PKU.DXHX202511041
5. [5]
  Xiyuan Zhang , Rui Dong , Yang Yang , Jiapeng Ding , Zhiwei Miao . Palladium-Catalyzed Tandem Cyclization of 4-Vinylbenzoxazinone and Indene-2-carbaldehyde: A Comprehensive Organic Chemistry Experiment. University Chemistry, 2025, 40(9): 361-367. doi: 10.12461/PKU.DXHX202410062
6. [6]
  Haolin Yang , Aoxiang Fan , Yi Song , Yang Chen . 基于甲酰化-共轭脱氢串联策略的苯并呋喃-5-甲醛的制备——推荐一个基础有机合成综合性教学实验. University Chemistry, 2026, 41(5): 141-148. doi: 10.12461/PKU.DXHX202511156
7. [7]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
8. [8]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
9. [9]
  Xiaogang Liu , Mengyu Chen , Yanyan Li , Xiantao Ma . Experimental Reform in Applied Chemistry for Cultivating Innovative Competence: A Case Study of Catalytic Hydrogen Production from Liquid Formaldehyde Reforming at Room Temperature. University Chemistry, 2025, 40(7): 300-307. doi: 10.12461/PKU.DXHX202408007
10. [10]
  Chengxin Chen , Hongfei Shi , Xiaoyan Cai , Liang Mao , Zhe Chen . Enhanced bifunctional photocatalytic performances for H₂ evolution and HCHO elimination with an S-scheme CoWO₄/CdIn₂S₄ heterojunction. Acta Physico-Chimica Sinica, 2025, 41(12): 100155-0. doi: 10.1016/j.actphy.2025.100155
11. [11]
  Zhenhuan Wang , Weifei Wei , Ruijie Ma , Dou Luo , Zhanxiang Chen , Jun Zhang , Liyang Yu , Gang Li , Zhenghui Luo . 苯并[a]苯嗪受体的核心氰基化实现高效(19.04%)绿色溶剂加工的二元有机太阳能电池. Acta Physico-Chimica Sinica, 2026, 42(2): 100182-0. doi: 10.1016/j.actphy.2025.100182
12. [12]
  Yiling Wu , Peiyao Jin , Shenyue Tian , Ji Zhang . The Star of Sugar Substitutes: An Interview of Erythritol. University Chemistry, 2024, 39(9): 22-27. doi: 10.12461/PKU.DXHX202404034
13. [13]
  Xiaoyong ZHAI , Yao KOU , Pingru SU , Yu TANG . Lanthanide metal-organic framework with msw topology: Synthesis and the application in 2, 4, 6-trinitrophenol detection. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2087-2094. doi: 10.11862/CJIC.20250182
14. [14]
  Youlin SI , Shuquan SUN , Junsong YANG , Zijun BIE , Yan CHEN , Li LUO . Synthesis and adsorption properties of Zn(Ⅱ) metal-organic framework based on 3, 3', 5, 5'-tetraimidazolyl biphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1755-1762. doi: 10.11862/CJIC.20240061
15. [15]
  Xi Tan , Chunhong Chen , Lijia Leng , Yulong Zhang . 二苯甲烷制备实验改进研究与拓展. University Chemistry, 2026, 41(5): 159-169. doi: 10.12461/PKU.DXHX202511049
16. [16]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, 2024, 39(6): 287-294. doi: 10.3866/PKU.DXHX202310073
17. [17]
  Tianjiao Hu , Jie Zhang , Juan Xie , Jin Li , Mianjue Wang . 葡萄酒中有“钻石”？！——关于酒石酸家族的科普实验. University Chemistry, 2026, 41(5): 340-349. doi: 10.12461/PKU.DXHX202511013
18. [18]
  Min LIU , Huapeng RUAN , Zhongtao FENG , Xue DONG , Haiyan CUI , Xinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362
19. [19]
  Yuhang Jiang , Weijie Liu , Jiaqi Cai , Jiayue Chen , Yanping Ren , Pingping Wu , Liulin Yang . A Journey into the Science and Art of Sugar: “Dispersion of Light and Optical Rotation of Matter” Science Popularization Experiment. University Chemistry, 2024, 39(9): 288-294. doi: 10.12461/PKU.DXHX202401054
20. [20]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(1110)
HTML views(211)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return