Home

Citation: GUO Hong-Xia, LIU Ya-Yan, WANG Lan, ZENG Xiong-Hui, HAO Xian, LI Ying. Preparation of Nanocrystalline Pb(Zr_0.52Ti_0.48)O₃ by Sol-Gel Process[J]. Chinese Journal of Applied Chemistry, ;2002, 19(12): 1166-1169. shu

Preparation of Nanocrystalline Pb(Zr_0.52Ti_0.48)O₃ by Sol-Gel Process

1.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Corresponding author: LIU Ya-Yan,
Received Date: 23 May 2002
Available Online: 26 September 2002

Nanocrystalline Pb(Zr_0.52Ti_0.48)O₃ was prepared from lead acetate, zirconium oxynitrate and tetrabutyltitanate by a sol-gel method. It is found that both the crystallization temperature of precursor PZT and PZT product size were increased with increase of V(C₃H₈O₂)/V(H₂O) ratio in solution used. At V(C₃H₈O₂)/V(H₂O)=4.47 the gel was formed moderately quick, and the nanocrystalline PZT with uniform granularity and low crystallization temperature could be obtained. The diameter of the final nanocrystalline was ranged in 60~70 nm as measured by atomic force microscopy(AFM). The crystallization temperature of the precursor PZT was 443℃ and the crystallization reaction was completed at 500℃ by DTA and TG. The sol-gel reaction process was monitored by FT-IR and XRD.
- Pb(Zr_0.52Ti_0.48)O₃,
- sol-gel process,
- nanocrystalline
1. [1]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
2. [2]
  Xiaokang JIANG , Junliang MA , Yan ZHAO , Feng GAO , Changli LIU , Xingshen ZHAO , Hengwei ZHOU . Preparation and luminescent properties of Sm³⁺-doped La₂MgZrO₆ phosphors. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 263-270. doi: 10.11862/CJIC.20250236
3. [3]
  Yinyin Qian , Rui Xu . Utilizing VESTA Software in the Context of Material Chemistry: Analyzing Twin Crystal Nanostructures in Indium Antimonide. University Chemistry, 2024, 39(3): 103-107. doi: 10.3866/PKU.DXHX202307051
4. [4]
  Lijun Yue , Siya Liu , Peng Liu . 不同晶相纳米MnO₂的制备及其对生物乙醇选择性氧化催化性能的测试——一个科研转化的综合化学实验. University Chemistry, 2025, 40(8): 225-232. doi: 10.12461/PKU.DXHX202410005
5. [5]
  Jian Li , Yu Zhang , Rongrong Yan , Kaiyuan Sun , Xiaoqing Liu , Zishang Liang , Yinan Jiao , Hui Bu , Xin Chen , Jinjin Zhao , Jianlin Shi . Highly Efficient, Targeted, and Traceable Perovskite Nanocrystals for Photoelectrocatalytic Oncotherapy. Acta Physico-Chimica Sinica, 2025, 41(5): 100042-0. doi: 10.1016/j.actphy.2024.100042
6. [6]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107
7. [7]
  Ximeng CHI , Jianwei WEI , Yunyun WANG , Wenxin DENG , Jiayi DAI , Xu ZHOU . First-principles study of the electronic structure and optical properties of Au and I doped-inorganic lead-free double perovskite Cs₂NaBiCl₆. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1371-1379. doi: 10.11862/CJIC.20240401
8. [8]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂ Nanosheets Improved the Buried Interface for Perovskite Solar Cells. Acta Physico-Chimica Sinica, 2025, 41(3): 100029-0. doi: 10.3866/PKU.WHXB202407025
9. [9]
  Wenjun Yang , Qiaoling Tan , Wenjiao Xie , Xiaoyu Pan , Youyong Yuan . Construction and Characterization of Calcium Alginate Microparticle Drug Delivery System: A Novel Design and Teaching Practice in Polymer Experiments. University Chemistry, 2025, 40(3): 371-380. doi: 10.12461/PKU.DXHX202405150
10. [10]
  Cheng PENG , Jianwei WEI , Yating CHEN , Nan HU , Hui ZENG . First principles investigation about interference effects of electronic and optical properties of inorganic and lead-free perovskite Cs₃Bi₂X₉ (X=Cl, Br, I). Chinese Journal of Inorganic Chemistry, 2024, 40(3): 555-560. doi: 10.11862/CJIC.20230282
11. [11]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
12. [12]
  Zisu Fang , Shida Hou , Yuxuan Gong , Jing Yan , Rui Bian , Dingwen Wang , Yi Yan . Defending the Zirconium Kingdom: An Elemental Adventure. University Chemistry, 2026, 41(2): 323-327. doi: 10.12461/PKU.DXHX202503071
13. [13]
  Yuan Zheng , Quan Lan , Zhenggen Zha , Lingling Li , Jun Jiang , Pingping Zhu . Teaching Reform of Organic Synthesis Experiments by Introducing Reverse Thinking and Design Concepts: Taking the Synthesis of Cinnamic Acid Based on Retrosynthetic Analysis as an Example. University Chemistry, 2024, 39(6): 207-213. doi: 10.3866/PKU.DXHX202310065
14. [14]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . Architecting Inorganic/Organic S-Scheme Heterojunction of Bi₄Ti₃O₁₂ Coupling with g-C₃N₄ for Photocatalytic H₂O₂ Production from Pure Water. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-0. doi: 10.3866/PKU.WHXB202403009
15. [15]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . Accelerated Interfacial Electron Transfer in Perovskite Solar Cell by Ammonium Hexachlorostannate Modification and fs-TAS Investigation. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-0. doi: 10.3866/PKU.WHXB202402006
16. [16]
  Shantao Zhang , TianAo Hou , Yandong Wang , Zhimin Fang , Yu Wu , Haolin Wang , Tao Chen , Shuang Chen , Wenhua Zhang , Shengzhong (Frank) Liu , Shangfeng Yang . π-Conjugation-extended dinaphthocarbazole phosphonic acid as a hole-selective layer for inverted perovskite solar cells. Acta Physico-Chimica Sinica, 2026, 42(3): 100194-0. doi: 10.1016/j.actphy.2025.100194
17. [17]
  Kexin Yan , Zhaoqi Ye , Lingtao Kong , He Li , Xue Yang , Yahong Zhang , Hongbin Zhang , Yi Tang . Seed-Induced Synthesis of Disc-Cluster Zeolite L Mesocrystals with Ultrashort c-Axis: Morphology Control, Decoupled Mechanism, and Enhanced Adsorption. Acta Physico-Chimica Sinica, 2024, 40(9): 2308019-0. doi: 10.3866/PKU.WHXB202308019
18. [18]
  Xin Han , Zhihao Cheng , Jinfeng Zhang , Jie Liu , Cheng Zhong , Wenbin Hu . Design of Amorphous High-Entropy FeCoCrMnBS (Oxy) Hydroxides for Boosting Oxygen Evolution Reaction. Acta Physico-Chimica Sinica, 2025, 41(4): 100033-0. doi: 10.3866/PKU.WHXB202404023
19. [19]
  Zhou Fang , Zhihao Zhang , Weihan Jiang , Kin Shing Chan . Warfarin: From Poison to Cure, the Remarkable Journey of a Molecule. University Chemistry, 2025, 40(4): 326-330. doi: 10.12461/PKU.DXHX202406038
20. [20]
  Zhi Zheng , Qi Ma , Feiyang Liu , Gukui Chen , Junlong Zhao . Defeating Dental Plaque with Science: Unlocking the Power of Biofilm Management. University Chemistry, 2026, 41(2): 295-300. doi: 10.12461/PKU.DXHX202502088

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(512)
HTML views(37)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

Preparation of Nanocrystalline Pb(Zr0.52Ti0.48)O3 by Sol-Gel Process

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Nanocrystalline Pb(Zr_0.52Ti_0.48)O₃ by Sol-Gel Process