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Citation: ZHAO Jin, SONG Jin-Yong, WANG Chao-Jie, LIU Lei, SUN Xin-Qi. Synthesis of 3,4,5-Trimethoxybenzoylsolanesylamide[J]. Chinese Journal of Applied Chemistry, ;2003, 20(1): 95-97. shu

Synthesis of 3,4,5-Trimethoxybenzoylsolanesylamide

1.
Henan University Key Laboratory of Special Functional Materials, Kaifeng 475001

Corresponding author: ZHAO Jin,
Received Date: 19 June 2002
Available Online: 10 September 2002
Fund Project: 河南省科委攻关资助项目(0124090421) (0124090421)

3,4,5-Trimethoxybenzoyloxysolanesylamide(8) was first synthesized from solanesol in four steps. Thus, solanesyl bromide(5) prepared by the reaction of solanesol(4) and PBr₃ was reacted with potassium phthalimide to give N-solanesylphthalimide(6), which was refluxed with N₂H₄·H₂O in 95% EtOH to give solanesylamine(7). Compound 7 was then reacted with 3,4,5-trimethoxybenzoyloxyl chloride to give the title compound. Its structure has been confirmed by IR, ¹H NMR, MS and elemental analysis.
- trimethoxybenzoylsolanesylamide,
- synthesis,
- solanesol,
- solanesylamine
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