Citation:
WANG Xiao-Dan, YANG Hua-Bin, MENG Xian-Ling, ZHANG Hai-Chang, ZHOU Zuo-Xiang. Electrochemical Properties of Calcium Zincate Synthesized by Ball-Milling Method[J]. Chinese Journal of Applied Chemistry,
;2003, 20(6): 528-531.
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Calcium zincate as an active material in Zn/Ni secondary battery has been successfully synthesized by ball-milling method.Its chemical composition Ca(OH)2·2Zn(OH)2·2H2O was confirmed by DTATG and XRD.The SEM microphotos indicated that calcium zincate obtained by ball-milling not only has smaller particles but also larger specific surface area than that prepared by chemical method.The calcium zincate prepared by ball milling has a better cyclic behavior and a higher discharge capacity than that prepared by chemical method.
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