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Citation: XIU Fu-Rong, REN Zhi-Gang, YUAN Ya-Xian, GU Jian-Sheng, DAI Jie. Electrochemical Preparation of Ag(PPh₃)_nX(n=1,2,3;X=Cl,Br,I)[J]. Chinese Journal of Applied Chemistry, ;2003, 20(8): 788-790. shu

Electrochemical Preparation of Ag(PPh₃)_nX(n=1,2,3;X=Cl,Br,I)

1.
Department of chemistry, Suzhou University, Suzhou 215006

Corresponding author: GU Jian-Sheng,
Received Date: 18 December 2002
Available Online: 23 May 2003
Fund Project: 国家自然科学基金资助课题(20071024) (20071024)

Some complexs of Ag(PPh₃)_nX(n=1,2,3;X=Cl,Br,I) were electrosynthesized using NH₄X or I₂ in non aqueous medium, in yield >95%. The mechanism of electrochemical reaction and the effect of material ratio on the complexes have been studied. When n(PPh₃):n(NH₄X)=3:1, Ag(PPh₃)₂X(X=Cl,Br) were obtained; when n(PPh₃):n(NH₄I/I₂)=1:1, AgPPh₃I was obtained; when n(PPh₃):n(NH₄I)=2:1 or 3:1, Ag(PPh₃)₃I was obtained. This method is better than the traditional chemical synthesis.
- silver complex,
- triphenylphosphine,
- electrosynthesis
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Electrochemical Preparation of Ag(PPh₃)_nX(n=1,2,3;X=Cl,Br,I)