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Citation: CHEN Chang-Yun, ZHOU Zhi-Hua, ZHOU Yi-Ming, LONG Qi. Solid State Synthesis of Triethanolammonium Tetrachloronickelate and Its Thermochromism[J]. Chinese Journal of Applied Chemistry, ;2003, 20(9): 914-916. shu

Solid State Synthesis of Triethanolammonium Tetrachloronickelate and Its Thermochromism

1.
a Department of Chemistry, Nanjing Xiaozhuang College, Nanjing 210017;
2.
b Department of Chemistry, Nanjing Normal University, Nanjing

Corresponding author: CHEN Chang-Yun,
Received Date: 10 January 2003
Available Online: 23 May 2003
Fund Project:

Triethanolammonium tetrachloronickelate was synhesized by a solid state reaction of triethanolamine hydrochloride with anhydrous nickel chloride. The compound undergoes a reversible thermochromism phase transition at ca.152℃. UV-visible, near-IR, IR spectra and elemental analysis results confirmed the structure of the product. It was deduced that thermochromism of the product is caused by the structural phase transition of the complex ion, NiCl₄^2-. The enthalpy change of phase transition for the product was 61.0 kJ/mol determinated by DSC.
- triethanolammonium tetrachloronickelate,
- thermochromism,
- solid state synthesis
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