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Citation: MA Wen, ZHANG Sheng-Yi, WU Jie-Ying, TIAN Yu-Peng, FUN Hoong-Kun. Solid State Synthesis, Structure and One-, Two-photon Fluorescence of Malononitrile Derivatives[J]. Chinese Journal of Applied Chemistry, ;2003, 20(9): 862-866. shu

Solid State Synthesis, Structure and One-, Two-photon Fluorescence of Malononitrile Derivatives

1.
a Department of Chemistry, Anhui University, Hefei 230039;
2.
b X-ray Crystallography Laboratory, School of Physics, University of Sceinces Malaysia, 11800 USM, Penang, Malaysia

Corresponding author: TIAN Yu-Peng,
Received Date: 10 January 2003
Available Online: 23 May 2003
Fund Project: 国家自然科学基金(50272001,20071001) (50272001,20071001)安徽省自然科学基金(03044701) (03044701)国家重大基础研究发展规划(1998061402)资助项目 (1998061402)

Three novel malononitrile derivatives have been synthesized by the solid state reaction at room temperature. The reactions are carried out for 0.5 h with yields all beyond 93%. The compounds have been characterized by IR、UV、¹H NMR and elemental analysis. The structure of the compound 3 is determined by X-ray diffraction analysis. The single-and double-photon fluorescence spectra of the compounds 2 and 3 are discussed. The results show that single-photon and double-photon fluorescences have similar solvent effect.
- malononitrile derivative,
- solid state synthesis,
- double-photon fluorescence
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