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Citation: HAN Jing-Li, CHEN Jian, LU Jiu-Fang, HE Xiang-Ming. Application of Mode Coupling Theory to Calculation of the Ionic Limiting Molar Conductivity[J]. Chinese Journal of Applied Chemistry, ;2003, 20(9): 845-848. shu

Application of Mode Coupling Theory to Calculation of the Ionic Limiting Molar Conductivity

1.
a Department of Chemical Engineering, Tsinghua University, Beijing 100084;
2.
b Institute of Nuclear Energy Technology, Tsinghua University, Beijing 102201

Corresponding author: HAN Jing-Li,
Received Date: 29 December 2002
Available Online: 14 April 2003
Fund Project: 清华大学基础研究基金(200115007)资助项目 (200115007)

The ion transfer number is introduced in the formula describing the relationship between ionic limiting molar conductivity and ionic concentration based on mode coupling theory(MCT). A series of calculated for the ionic limiting molar conductivity are present. The ionic limiting molar conductivities of seven lithium salts in two single organic solvents and two mixed solvents are calculated. The results are in good agreement with the literature's results which are calculated either from transport number obtained by empirical formula or from transport number obtained by electrochemiscal experiments.
- mode coupling theory,
- ion limiting molar conductivity,
- organic electrolyte solution,
- lithium salt
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