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Citation: TAO Jian-Qing, YU Zhi, SHAO Ting, WANG Tian-Wei, YOU Xiao-Zeng. Syntheses and Magnetic Properties of 1',8'-Diaza-anthreceno-[a,5,6]-1,10-phenanthroline and Its Fe(Ⅱ) Complex[J]. Chinese Journal of Applied Chemistry, ;2003, 20(11): 1102-1104. shu

Syntheses and Magnetic Properties of 1',8'-Diaza-anthreceno-[a,5,6]-1,10-phenanthroline and Its Fe(Ⅱ) Complex

1.
a Department of Chemistry, Yancheng Teachers College, Yancheng 224002;
2.
b State Key Laboratory of Coordination Chemistry, Institute of Coordination Chemistry, Nanjing University, Nanjing

Corresponding author: TAO Jian-Qing,
Received Date: 12 March 2003
Available Online: 23 May 2003
Fund Project: 国家自然科学基金项目(G2001004) (G2001004)江苏省教育厅自然科学基金项目(02KJB150010) (02KJB150010)

A new large conjugated ligand 1',8'-diaza-anthreceno-[a,5,6]-1,10-phenanthroline(dap) and its Fe(Ⅱ) complex have been synthesized from phenanthroline and 2,3-diaminonphthalene. The structures and properties of the ligand and the complex were characterized by elemental analysis, IR, MS, UV-vis spectrometry. The study of magnetic susceptibility of the complex indicated the complex lies mainly in low spin state between 80~300 K, while a spin crossover occurs in high temperature region as a result of the stronger ligand field of this ligand than those of dipyrido[3,2-a:2'3'-c] phenazine and dipyrazine[2,3f:2',3'h] quinoxaline.
- diaza anthreceno phenanthroline,
- magnetic susceptibility,
- spin crossover
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