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Citation: YU Zhang-Yu, QI Li-Yun, QIN Mei, GUO Dao-Jun, WANG Hui-Yun. Decomposition Mechanism of Hydrogen Peroxide Catalyzed by Ferrocene in Toluene-Ethanol Mixed Solution[J]. Chinese Journal of Applied Chemistry, ;2004, 21(1): 41-44. shu

Decomposition Mechanism of Hydrogen Peroxide Catalyzed by Ferrocene in Toluene-Ethanol Mixed Solution

YU Zhang-Yu ^a,, ,
QI Li-Yun ^a,b ,
QIN Mei ^a ,
GUO Dao-Jun ^a ,
WANG Hui-Yun ^c

1.
a Department of Chemistry, Qufu Normal University, Qufu 273165;
2.
b Institute of Chemistry, Chinese Academy of Sciences, Beijing;
3.
c College of Chemical Engineering, University of Petroleum, Beijing Campus, Beijing

Corresponding author: YU Zhang-Yu,
Received Date: 25 March 2003
Available Online: 10 October 2003
Fund Project: 国家自然科学基金(29673025) (29673025)山东省自然科学基金(Y2000B03)资助项目 (Y2000B03)

The electrochemical behavior of ferrocene in the absence and presence of hydrogen peroxide in toluene-ethanol mixed solutions were investigated at a platinum electrode by cyclic voltammetry and AC impedance measurements. The results show that increasing toluene in the solution mixture leads to increase of both solution resistance and electrochemical reaction resistance of ferrocene at the Pt electrode. Ferricinium ion could react with hydrogen peroxide in the liquid phase. The electrode process is considered to be followed by catalytic EC(electron transfer-chemical reaction) mechanism.
- toluene-ethanol mixture,
- ferrocene,
- hydrogen peroxide,
- electron transfer mechanism
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