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Citation: LIU Xiong-Min, HASEGAWA Kazutoshi, TAMURA Masamitsu. Effects of Dilute Stabilizing Agents on the Thermal Decomposition Pressure of Organic Peroxides[J]. Chinese Journal of Applied Chemistry, ;2004, 21(6): 589-592. shu

Effects of Dilute Stabilizing Agents on the Thermal Decomposition Pressure of Organic Peroxides

1.
a Industrial Testing & Experiment Center, Guangxi University, Nanning 530004;
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b National Research Institute of Fire and Disaster, Tokyo, Japan;
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c Institute of Environmental Studies, Graduate School of Frontier, The University of Tokyo, Tokyo, Japan

Corresponding author: LIU Xiong-Min,
Received Date: 18 July 2003
Available Online: 20 November 2003
Fund Project: 教育部留学回国人员科研启动基金资助项目(教外司[1997]436) (教外司[1997]436)

Pressure behavior and pressure effect of dilute stabilizing agents in the thermal decomposition of organic peroxides were examined in a mini-closed pressure vessel test(MCPVT). The maximal pressure of thermal decomposition(P_max) reduced when stabilizing agent was non-volatile, and P_max increased when stabilizing agent was a volatile, and (dP/dt)_max was reduced. The stabilizing effects of stabilizing agent on the thermal decomposition were evaluated with (dP/dt)_max and K(K=(dP/dt)_max,_D/(dP/dt)_max(D:dilute stabilizing agent). The order of K was BPO-H₂ < ODCP-CaCO₃ < DTBP-IPS < TBPB-IPS, when mass fraction of organic peroxides was 0.6 and K was equal to 0.748 2, 0.316 1, 0.242 3, 0.182 7.
- organic peroxide,
- thermal decomposition,
- stabilizing agent,
- mini-closed pressure vessel test,
- pressure behavior
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