Home

Citation: GONG Ya-Feng, ZHANG Zi-Yong, ZHANG Ai-Feng. Dual Grafting of MAH/styrene onto Polypropylene Using Supercritical CO₂ Fluid[J]. Chinese Journal of Applied Chemistry, ;2004, 21(9): 914-917. shu

Dual Grafting of MAH/styrene onto Polypropylene Using Supercritical CO₂ Fluid

1.
Department of Chemistry, College of Life Science and Technology, Jinan University, Guangzhou 510632

Corresponding author: ZHANG Zi-Yong,
Received Date: 31 October 2003
Available Online: 10 April 2004
Fund Project: 广东省自然科学基金(021198)资助项目 (021198)

Free-radical dual grafting of maleic anhydride(MAH) and styrene(St) onto granular polypropylene(PP) using supercritical CO₂ as a solvent and swelling agent has been studied and PP-g-(MAH-St) prepared. The effect of molar ratio of monomers, swelling temperature and time, reaction time and pressure on the grafting density are discussed. It is found that the St as a co-monomer in the grafting reaction system could significantly enhance the grafting density of PP for MAH and St on PP. The maximum grafting density for PP-g-(MAH-St) in supercritical CO₂ fluid under optimal reaction conditions was 10.58%, two times that for PP-g-MAH. The process is simpler than regular graft polymerization processes. The structures and properties of the graft copolymers were characterized by FTIR and DSC. The results indicate that styrene branch chains reduces the T_m of PP from 158℃ to 154℃.
- polypropylene,
- graft,
- supercritical CO₂,
- styrene,
- maleic anhydride
1. [1]
  Chengqian Mao , Yanghan Chen , Haotong Bai , Junru Huang , Junpeng Zhuang . Photodimerization of Styrylpyridinium Salt and Its Application in Silk Screen Printing. University Chemistry, 2024, 39(5): 354-362. doi: 10.3866/PKU.DXHX202312014
2. [2]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
3. [3]
  Ling Fan , Meili Pang , Yeyun Zhang , Yanmei Wang , Zhenfeng Shang . Quantum Chemistry Calculation Research on the Diels-Alder Reaction of Anthracene and Maleic Anhydride: Introduction to a Computational Chemistry Experiment. University Chemistry, 2024, 39(4): 133-139. doi: 10.3866/PKU.DXHX202309024
4. [4]
  Zeyi Yan , Ruitao Liu , Xinyu Qi , Yuxiang Zhang , Lulu Sun , Xiangyuan Li , Anchao Feng . Exploration of Suspension Polymerization: Preparation and Fluorescence Stability of Perovskite Polystyrene Microbeads. University Chemistry, 2025, 40(4): 72-79. doi: 10.12461/PKU.DXHX202405110
5. [5]
  Ruoqian Zhang , Chaoqun Mu , Yali Hou , Mingming Zhang . 四苯乙烯基多组分金属有机笼的构筑及其固态发光性能研究. University Chemistry, 2025, 40(8): 277-283. doi: 10.12461/PKU.DXHX202410027
6. [6]
  Zijian Zhao , Yanxin Shi , Shicheng Li , Wenhong Ruan , Fang Zhu , Jijun Jiang . A New Exploration of the Preparation of Polyacrylic Acid by Free Radical Polymerization Based on the Concept of Green Chemistry. University Chemistry, 2024, 39(5): 315-324. doi: 10.3866/PKU.DXHX202311094
7. [7]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
8. [8]
  Qingyu Yang , Yuanhai Yu , Yanliu Wu , Ting Yang , Le Zhong , Wenhong Ruan , Jie Li . Digital Intelligence-Empowered Exploration of Copolymerized Polyacrylonitrile Synthesis and Application Experiments for Carbon Fiber Precursors. University Chemistry, 2026, 41(1): 41-56. doi: 10.12461/PKU.DXHX202506010
9. [9]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
10. [10]
  Wenwen Ma , Lian Kong , Jinyang Chu , Li Ma , Ziqing Ma , Heyu Cheng , Xinyuan Li , Zhan Yu , Zhen Zhao . Digitalization-Driven Olefin Production: Digital Design of Catalysts for CO₂-Assisted Oxidation Dehydrogenation of Ethane to Ethylene. University Chemistry, 2026, 41(1): 363-372. doi: 10.12461/PKU.DXHX202506055
11. [11]
  Zhuoyan Lv , Yangming Ding , Leilei Kang , Lin Li , Xiao Yan Liu , Aiqin Wang , Tao Zhang . Light-Enhanced Direct Epoxidation of Propylene by Molecular Oxygen over CuO_x/TiO₂ Catalyst. Acta Physico-Chimica Sinica, 2025, 41(4): 100038-0. doi: 10.3866/PKU.WHXB202408015
12. [12]
  Hongli CHEN , Ziling XU , Shiwen DU , Ting WANG , Liguang WU . Controlled preparation of HKUST-1 based on polyvinylpyrrolidone and CO₂ separation performance of its doped mixed-matrix membranes. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 571-583. doi: 10.11862/CJIC.20250263
13. [13]
  Hong Dong , Feng-Ming Zhang . Covalent organic frameworks for artificial photosynthetic diluted CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100307-100307. doi: 10.1016/j.cjsc.2024.100307
14. [14]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
15. [15]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
16. [16]
  Mingming Zhang , Ting Xu , Ruonan Yin , Xueqiu Chen , Zheng-Jun Wang , Jun Li , Xin Wang , Huile Jin , Haibo Ke , Shun Wang , Jing-Jing Lv . Anode engineering for electrocatalytic CO₂ reduction reaction. Chinese Chemical Letters, 2026, 37(3): 110665-. doi: 10.1016/j.cclet.2024.110665
17. [17]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
18. [18]
  Hui Bian , Xinyi Yuan , Nan Zhang , Zhuo Xu , Juhong Lian , Ruibin Jiang , Junqing Yan , Deng Li , Shengzhong (Frank) Liu . Correlating vacancy-defect density with CO₂ activation for promoted CO₂ methanation over CsPbBr₃ photocatalyst. Chinese Chemical Letters, 2025, 36(7): 111034-. doi: 10.1016/j.cclet.2025.111034
19. [19]
  Xiaofan ZHANG , Yu DUAN , Meijie SHI , Nan LU , Renhong LI , Xiaoqing YAN . Z-scheme Co₃O₄/BiOBr heterojunction for efficient photoreduction CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(9): 1878-1888. doi: 10.11862/CJIC.20250079
20. [20]
  Muzi Li , Xin Zhang , Xiang-Jing Kong , Qiancheng Chen , Xuefeng Bai , Tao He , Jian-Rong Li . Ion exchange for enhancing MOF adsorbents performance in humid C₂H₂/CO₂ separation. Chinese Chemical Letters, 2026, 37(3): 110709-. doi: 10.1016/j.cclet.2024.110709

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(601)
HTML views(41)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

Dual Grafting of MAH/styrene onto Polypropylene Using Supercritical CO2 Fluid

Metrics

通讯作者: 陈斌, bchen63@163.com

Dual Grafting of MAH/styrene onto Polypropylene Using Supercritical CO₂ Fluid