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Citation: YIN Shou-Chun, XU Hong-Yao, TANG Ben-Zhong. Recent Advances in Synthesis of Terminal Aryl Acetylenes by Palladium-Catalyzed Coupling-Elimination Reaction[J]. Chinese Journal of Applied Chemistry, ;2004, 21(10): 973-979. shu

Recent Advances in Synthesis of Terminal Aryl Acetylenes by Palladium-Catalyzed Coupling-Elimination Reaction

1.
a School of Chemistryand Chemical Engineering, Anhui University, Hefei 230039;
2.
b Department of Chemistry, Hong Kong University of Scienceand Technology, Hong Kong

Corresponding author: XU Hong-Yao,
Received Date: 19 November 2003
Available Online: 20 April 2004
Fund Project: 国家自然科学基金(50073001,90206014) (50073001,90206014)安徽省优秀青年基金(04044060) (04044060)安徽省教委自然科学基金(2003kj016) (2003kj016)

As important organic intermediates, terminal aryl acetylenes have been widely applied in the organic and polymer field. The effect of reactants(alkynylzinc reagents and aryl halides reagent), catalysts(palladium-catalyst and cocatalyst) and other reaction conditions on the synthesis of terminal aryl acetylene are reviewed. The reaction mechanisms of palladium catalyzed coupling elimination reaction are discussed, showing that palladium-catalyzed coupling-elimination reaction is an effective method in the synthesis of the terminal aryl acetylene.
- aryl acetylene,
- coupling reaction,
- palladium-catalyst,
- synthesis,
- review
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