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Citation: YU Zhang-Yu, QIN Mei, QI Li-Yun, WANG Han-Qing, WANG Hui-Yun. Electron-Transfer Properties of Ferrocene and Influence of Hydrogen Peroxide on Them in Antiknock Additive for Gasoline[J]. Chinese Journal of Applied Chemistry, ;2004, 21(12): 1229-1232. shu

Electron-Transfer Properties of Ferrocene and Influence of Hydrogen Peroxide on Them in Antiknock Additive for Gasoline

YU Zhang-Yu ^a,c,, ,
QIN Mei ^b ,
QI Li-Yun ^b ,
WANG Han-Qing ^a ,
WANG Hui-Yun ^b

1.
a Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou;
2.
b Department of Chemistry, Qufu Normal University, Qufu 273165;
3.
c Graduate School of the Chinese Academy of Science, Beijing

Corresponding author: YU Zhang-Yu,
Received Date: 27 February 2004
Available Online: 12 July 2004
Fund Project: 国家自然科学基金(29673025) (29673025)山东省自然科学基金(Y2000B03)资助项目 (Y2000B03)

The auxiliaries of gasoline antiknock additive TKC were analysed by means of gas chromatography/mass spectrometry. The main auxiliary components were found to be toluene, dichloroethane, tetrachloroethy-lene, and butyl acetate. The electrochemical properties of ferrocene in the auxiliary additive in the presence and the absence of hydrogen peroxide were investigated at a platinum electrode by cyclic voltammetry. The electrode processes and cooperative effect of the additive components were determined. All the electrode reactions in the various media followed the catalytic EC(electron transfer-chemical reaction) mechanism.
- ferrocene,
- hydrogen peroxide,
- electron transfer mechanism,
- antiknock additive
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