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Citation: WANG Peng, JIANG Shu-Ren, JIANG Wei, ZHOU Wen-Jing, WANG Qiu-Xia, WANG Ping, ZHOU Zhi-Qiang. Enantiomeric Separation of Flutriafol by HPLC[J]. Chinese Journal of Applied Chemistry, ;2005, 22(4): 445-447. shu

Enantiomeric Separation of Flutriafol by HPLC

1.
Department of Applied Chemistry, College of Science, China Agricultural University, Beijing 100094

Corresponding author: ZHOU Zhi-Qiang,
Received Date: 18 June 2004
Available Online: 18 December 2004
Fund Project: 国家自然科学基金资助项目(20377052) (20377052)

The two enantiomers of flutriafol were resolved by means of high-performance liquid chromato-graphy with a cellulose derivative chiral stationary phase.The mobile phase was n-hexane,and five alkane alcohols were used as the polar modifier.The effects of the modifier and its concentration on the resolution were studied,and the influence of the temperature was also investigated.The results show that the separation factor could reach 1.41 at room temperature with 5% (volume fraction) isopropanol in the mobile phase.Lower column temperature resulted in a higher separation factor.The separation mechanism was primarily discussed.
- flutriafol,
- enantiomer,
- separation,
- chiral stationary phase
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