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Citation: WEI Xi-Lian, YIN Bao-Lin, SUN De-Zhi, LI Gan-Zuo. Interaction Between Sodium Dodecyl Sulfate and 3-Alkoxyl-2-hydroxypropyl Trimethyl Ammonium Chloride in Aqueous Systems[J]. Chinese Journal of Applied Chemistry, ;2005, 22(4): 427-430. shu

Interaction Between Sodium Dodecyl Sulfate and 3-Alkoxyl-2-hydroxypropyl Trimethyl Ammonium Chloride in Aqueous Systems

1.
a College of Chemistry & Chemical Engineering, Liaocheng University, Liaocheng 252059;
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b Kay Laboratory for Colloid and Interface Chemistry, Minstry of Education, Shandong University, Ji'nan

Corresponding author: WEI Xi-Lian,
Received Date: 28 June 2004
Available Online: 26 November 2004

The interaction between sodium dodecyl sulfate (SDS) and 3-alkoxyl-2-hydroxypropyl trimethyl ammonium chloride (C_nNCl) in aqueous systems was investigated by means of microcalorimetric titration.The pseudo-critical micellar concentration (pcmc) and thermodynamic parameters for the formation of the micelle of each mixture surfactant system were estimated from the calorimetric data and the titration curve.The formation enthalpy and entropy of the mixture micelle are discussed based on the structure of the surfactant using the iceberg model.The results show that the interaction between the hydrophobic chains of the SDS and the C_nNCl is more important than the mutual electrostatic attraction between the negatively charged end group of SDS and the positively charged end of C_nNCl in the synergistic interaction between the anionic and cationic surfactants.
- microcalorimetry,
- alkoxylhydroxypropyl trimethyl ammonium chloride,
- sodium dodecyl sulfate,
- micelle,
- hydrophobic interaction
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