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Citation: LIU Jing, LI Yuan-Gang, HE Jian-Ying, FANG Yu. The Interaction Between N,N'-Bis (ferrocenoyl)-diaminoethane and β-Cyclodextrin[J]. Chinese Journal of Applied Chemistry, ;2005, 22(4): 395-398. shu

The Interaction Between N,N'-Bis (ferrocenoyl)-diaminoethane and β-Cyclodextrin

1.
School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an 710062

Corresponding author: FANG Yu,
Received Date: 15 July 2004
Available Online: 29 September 2004
Fund Project: 国家自然科学基金资助项目(20373039) (20373039)教育部重点资助课题(03148) (03148)

The host-guest interaction between N,N'-bis (ferrocenoyl) diaminoethane and β-cyclodextrin (β-CD) was studied.The absorption intensity of the solution containing N,N'-bis (ferrocenoyl) diaminoethane and β-CD increased with the increase of the β-CD concentration.The introduction of N,N'-bis (ferrocenoyl) diaminoethane altered the fluorescence emission spectrum of the β-CD and pyrene system.Only one oxidative peak was found in the cyclic voltammogram of the mixture of N,N'-bis (ferrocenoyl) diaminoethane with β-CD,and the oxidation potential was significantly greater than that of the electro-active compound N,N'-bis (ferrocenoyl) diaminoethane in free state.These results show that as a guest,the two ferrocene groups in N,N'-bis (ferrocenoyl) diaminoethane can combine with β-CD simultaneously.
- ferrocene,
- β-cyclodextrin,
- host-guest interaction
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