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Citation: FENG Ting, LIU Lang, ZHANG Li, JIA Dian-Zeng. Solid-state and Liquid-state Syntheses and Characterization of Cu(Ⅱ) Complexes of Pyrazolone Derivatives[J]. Chinese Journal of Applied Chemistry, ;2005, 22(4): 372-376. shu

Solid-state and Liquid-state Syntheses and Characterization of Cu(Ⅱ) Complexes of Pyrazolone Derivatives

1.
Institute of Applied Chemistry, Xinjiang University, Urumqi 830046

Corresponding author: JIA Dian-Zeng,
Received Date: 6 July 2004
Available Online: 10 October 2004
Fund Project: 国家自然科学基金资助项目(20262005,20366005) (20262005,20366005)

Several Cu(Ⅱ) complexes were synthesized by solid-state reaction and liquid-state reaction of pyrazolone derivatives with cupric acetate,respectively,and characterized by elemental analysis,IR,TG-DTA and XRD techniques.The results show that the solid-state reaction and liquid-state reaction leadto different products.The molecular formulae of the liquid-state reaction products are M₂L₂·nH₂O(n=0,1) or M(HL)₂H₂O,and those of the solid-state reaction products are M(H₂L)·2OAc·nH₂O(n=1,2).
- pyrazolone,
- Cu(Ⅱ) complex,
- solid-state reaction
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