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Citation: WU Zhen-Yi, DENG Xiao-Shuang, LIN Yong-Sheng, YANG Sen-Gen, CHENG Da-Dian, ZHAN Meng-Xiong. Synthesis and Photoelectric Porperty of C₆₀Pd(Ph₂POCH₂CH₂OPPh₂)[J]. Chinese Journal of Applied Chemistry, ;2005, 22(9): 971-975. shu

Synthesis and Photoelectric Porperty of C₆₀Pd(Ph₂POCH₂CH₂OPPh₂)

1.
Department of Chemistry, Xiamen University, Xiamen 361005

Corresponding author: WU Zhen-Yi,
Received Date: 6 November 2004
Available Online: 12 April 2005
Fund Project: 福建省自然科学基金(E0410001,E0110002) (E0410001,E0110002)

C₆₀Pd(Ph₂POCH₂CH₂OPPh₂) complex was prepared in inert atmosphere via replacement reaction and characterized by mean of elemental analysis,IR,electronic spectra,XPS and XRD methods.The redox properties and thermostability of the title complex were studied,moreover the photovoltaic effect for C₆₀Pd(Ph₂POCH₂CH₂OPPh₂) complex to form n+n heterojunction on a GaAs electrode in photoelectrochemical cell was investigated.The result shows that I₃^-/I^- is the best redox couple in the photoelectrochemical cell.The photovoltaic property of C₆₀Pd(Ph₂POCH₂CH₂OPPh₂)-GaAs electrode at 1 μm for thickness of C₆₀Pd(Ph₂POCH₂CH₂OPPh₂) film is the best.
- fullerene,
- palladium complexe,
- photoelectric property
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Synthesis and Photoelectric Porperty of C₆₀Pd(Ph₂POCH₂CH₂OPPh₂)