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Citation: LI Ben-Gang, CHEN Zheng-Guo, GAO Qing, WANG Hai-Ping, LI Xiao-Qin. Synthesis and Surface Activity of SPPBGE[J]. Chinese Journal of Applied Chemistry, ;2005, 22(11): 1224-1229. shu

Synthesis and Surface Activity of SPPBGE

1.
Faculty of Chemistry and Material Science, Hubei University, The Hubei Province Key Laboratory of Polymer Materials, Wuhan 430062

Corresponding author: CHEN Zheng-Guo,
Received Date: 30 December 2004
Available Online: 18 April 2005
Fund Project: 湖北省教育厅自然科学重大研究资助项目(99A001) (99A001)

Four sodium poly(phenyl glycidyl ether)-co-poly(butyl glycidyl ether) sulfonates(SPPBGE) were synthesized via the sulfonation of the polyether with sulfuric acid.The molecular structure of SPPBGE can be controlled by adjusting the constituent of polyether and sulfonation degree of its pendant phenyl.Dynamic surface tensions of SPPBGE water solutions were measured via the plate method,the result shows that the dynamic surface activity increases with increasing butyl glycidyl ether content in SPPBGE.Critic micell concentrations and minimum surface tensions were determined via surface tension measurement,they are in the ranges of 1 400~780 mg/L and 47.77~32.05 mN/m respectively,and they decrease with increasing butyl glycidyl ether content in SPPBGE.Micell morphologies of SPPBGE in water were observed with TEM,they change with the concentration and molecular structure.
- sodium poly(phenyl glycidyl ether)-co-poly(butyl glycidyl ether)sulfonate,
- synthesis,
- surface(activity),
- micell
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