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Citation: TANG Xu-Dong, CHEN Xiao-Ting, ZHANG Ming-Zhu, HE Zheng-Hua, WANG Yan. Synthesis and Characterization of a Phosphorus-containing Polycarbonate with Bisphenol-A Moiety[J]. Chinese Journal of Applied Chemistry, ;2005, 22(12): 1360-1362. shu

Synthesis and Characterization of a Phosphorus-containing Polycarbonate with Bisphenol-A Moiety

1.
School of Material Science & Chemical Engineering, Tianjin University of Science & Techology, Tianjin 300222

Corresponding author: TANG Xu-Dong,
Received Date: 23 February 2005
Available Online: 22 May 2005
Fund Project: 国家自然科学基金资助项目(50203008) (50203008)

A novel phosphorus-containing copolycarbonate was synthesized from bisphenol-A,2-(6-oxido-6H-dibenz<1,2>oxa phosphorin-6-yl)-1,4-dihydroxy phenylene(ODOP-HQ) and triphosgene by interfacial polycondensation,and a copolycarbonate with an inherent viscosity of 0.53 dL/g was obtained.The copolymer was characterized by elemental analysis,FT-IR,DSC,TGA,and NMR.DSC result shows that the T_g of the copolycarbonate is 149℃,which is higher than that of normal PC.The TGA result shows that the onset decomposition temperature of the copolycarbonate is 355℃,which indicates it possesses a good thermal stability.
- polycarbonate,
- triphosgene,
- synthesis,
- flame retardancy
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