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Citation: FEI Xue-Ning, ZHANG Bao-Lian, SHI Bo-Jie, David J Berg. A Simple Synthesis Procedure for Allylphenol Derivatives[J]. Chinese Journal of Applied Chemistry, ;2006, 23(2): 221-223. shu

A Simple Synthesis Procedure for Allylphenol Derivatives

1.
a Department of Material Science and Engineering, Tianjin institute of Urban Construction, Tianfin 300384;
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b College of Material, Tianfin University, Tianjin;
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c University of Victoria, Canada, V8 W3 V6

Corresponding author: ZHANG Bao-Lian,
Received Date: 16 March 2005
Available Online: 30 July 2005

In a toluene/water heterogeneous system,4-methylphenyl allyl ether(Ⅰ) was obtained from the reaction between 4-methylphenol and allyl bromide with a high yield at 70℃ for 24 h in the presence of a phase transfer catalyst trioctadecyl methyl ammonium chloride and excess sodium hydroxide.Compound(Ⅰ) was converted into compound(Ⅳ) after Claisen rearrangement,etherification and Claisen rearrangement again.When the reaction lasted for 72 h, compounds(Ⅰ),(Ⅱ) and(Ⅲ) were obtained with the yields of 29%,50%,and 10%,respectively under the above reaction conditions.Compound(Ⅳ) was obtained from compound(Ⅲ) via Claisen rearrangement.
- phase transfer catalysis,
- Claisen rearrangement,
- methyldiallyl phenol
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